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Taula de potencials estàndards de reducció

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El potencial de reducció s'utilitza per determinar el potencial electroquímic o el potencial d'un elèctrode d'una cel·la electroquímica o d'una cel·la galvànica.

Aquests potencials de reducció venen donats en volts respecte d'un elèctrode estàndard d'hidrògen. Els valors dels potencials estàndards de reducció que es presenten a la taula han estat presos a una temperatura de 298 K, una pressió de 100 KPa i en una solució aquosa amb una concentració de 1 mol.[1][2][3][4]

Mitja reacció Eo (V)
Li+(aq) + e− → Li(s) −3.05
Rb+(aq) + e− → Rb(s) −2.98
K+(aq) + e− → K(s) −2.93
Cs+(aq) + e− → Cs(s) −2.92
Ba2+(aq) + 2e− → Ba(s) −2.91
Sr2+(aq) + 2e− → Sr(s) −2.89
Ca2+(aq) + 2e− → Ca(s) −2.76
Na+(aq) + e− → Na(s) −2.71
Mg2+(aq) + 2e− → Mg(s) −2.38
H2 + 2e− → 2H− −2.25
Be2+(aq) + 2e− → Be(s) −1.85
Al3+(aq) + 3e− → Al(s) −1.68
Ti2+(aq) + 2e− → Ti(s) −1.63
TiO(s) + 2H+ + 2e− → Ti(s) + H2O −1.31
Ti2O3(s) + 2H+ + 2e− → 2TiO(s) + H2O −1.23
Ti3+(aq) + 3e− → Ti(s) −1.21
Mn2+(aq) + 2e− → Mn(s) −1.18
V2+(aq) + 2e− → V(s) −1.13
Sn(s) + 4H+ + 4e− → SnH4(g) −1.07
SiO2(s) + 4H+ + 4e− → Si(s) + 2H2O −0.91
B(OH)3(aq) + 3H+ + 3e− → B(s) + 3H2O −0.89
TiO2+(aq) + 2H+ + 4e− → Ti(s) + H2O −0.86
2 H2O(l) + 2e– → H2(g) + 2 OH–(aq) −0.83
Zn2+(aq) + 2e− → Zn(s) −0.76
Cr3+(aq) + 3e− → Cr(s) −0.74
Au(CN)2–(aq) + e– → Au(s) +2 CN–(aq) −0.60
2TiO2(s) + 2H+ + 2e− → Ti2O3(s) + H2O −0.56
Ga3+(aq) + 3e− → Ga(s) −0.53
H3PO2(aq) + H+ + e− → P(s) + 2H2O −0.51
H3PO3(aq) + 3H+ + 3e− → P(s) + 3H2O −0.50
H3PO3(aq) + 2H+ + 2e− → H3PO2(aq) + H2O −0.50
Fe2+(aq) + 2e− → Fe(s) −0.44
2CO2(g) + 2H+(aq) + 2e– → HOOCCOOH(aq) −0.43
Cr3+(aq) + e− → Cr2+(aq) −0.42
2H+ + 2e− → H2 −0.41
Cd2+(aq) + 2e− → Cd(s) −0.40
PbSO4(s) + 2e– → Pb(s) +SO42-(aq) −0.36
GeO2(s) + 2H+ + 2e− → GeO(s) + H2O −0.37
In3+(aq) + 3e− → In(s) −0.34
Tl+(aq) + e− → Tl(s) −0.34
Ge(s) + 4H+ + 4e− → GeH4(g) −0.29
Co2+(aq) + 2e → Co(s) −0.28
H3PO4(aq) + 2H+ + 2e− → H3PO3(aq) + H2O −0.28
V3+(aq) + e− → V2+(aq) −0.26
Ni2+(aq) + 2e− → Ni(s) −0.25
As(s) + 3H+ + 3e− → AsH3(g) −0.23
MoO2(s) + 4H+ + 4e− → Mo(s) + 2H2O −0.15
Si(s) + 4H+ + 4e− → SiH4(g) −0.14
Sn2+(aq) + 2e− → Sn(s) −0.13
O2(g) + H+ + e− → HO2•(aq) −0.13
Pb2+(aq) + 2e− → Pb(s) −0.13
WO2(s) + 4H+ + 4e− → W(s) −0.12
CO2(g) + 2H+ + 2e− → HCOOH(aq) −0.11
Se(s) + 2H+ + 2e− → H2Se(g) −0.11
CO2(g) + 2H+ + 2e− → CO(g) + H2O −0.11
SnO(s) + 2H+ + 2e− → Sn(s) + H2O −0.10
SnO2(s) + 2H+ + 2e− → SnO(s) + H2O −0.09
WO3(aq) + 6H+ + 6e− → W(s) −0.09
P(s) + 3H+ + 3e− → PH3(g) −0.06
HCOOH(aq) + 2H+ + 2e− → HCHO(aq) + H2O −0.03
2H+(aq) + 2e− → H2(g) 0.00
H2MoO4(aq) + 6H+ + 6e− → Mo(s) + 4H2O +0.11
Ge4+(aq) + 4e− → Ge(s) +0.12
C(s) + 4H+ + 4e− → CH4(g) +0.13
HCHO(aq) + 2H+ + 2e− → CH3OH(aq) +0.13
S(s) + 2H+ + 2e− → H2S(g) +0.14
Sn4+(aq) + 2e− → Sn2+(aq) +0.15
Cu2+(aq) + e− → Cu+(aq) +0.16
HSO4−(aq) + 3H+ + 2e− → 2H2O(l) + SO2(aq) +0.16
SO42−(aq) + 4H+ + 2e− → 2H2O(l) + SO2(aq) +0.17
SbO+ + 2H+ + 3e− → Sb(s) + H2O +0.20
H3AsO3(aq) + 3H+ + 3e− → As(s) + 3H2O +0.24
GeO(s) + 2H+ + 2e− → Ge(s) + H2O +0.26
Bi3+(aq) + 3e− → Bi(s) +0.32
VO2+(aq) + 2H+ + e− → V3+(aq) +0.34
Cu2+(aq) + 2e− → Cu(s) +0.34
[Fe(CN)6]3−(aq) + e− → [Fe(CN)6]4−(aq) +0.36
O2(g) + 2H2O(l) + 4e– → 4OH–(aq) +0.40
H2MoO4 + 6H+ + 3e− → Mo3+(aq) +0.43
CH3OH(aq) + 2H+ + 2e− → CH4(g) + H2O +0.50
SO2(aq) + 4H+ + 4e− → S(s) + 2H2O +0.50
Cu+(aq) + e− → Cu(s) +0.52
CO(g) + 2H+ + 2e− → C(s) + H2O +0.52
I2(s) + 2e− → 2I−(aq) +0.54
I3−(aq) + 2e− → 3I−(aq) +0.54
[AuI4]−(aq) + 3e− → Au(s) + 4I−(aq) +0.56
H3AsO4(aq) + 2H+ + 2e− → H3AsO3(aq) + H2O +0.56
[AuI2]−(aq) + e− → Au(s) + 2I−(aq) +0.58
MnO4–(aq) + 2H2O(l) + 3e– → MnO2(s) + 4 OH–(aq) +0.59
S2O32− + 6H+ + 4e− → 2S(s) + 3H2O +0.60
H2MoO4(aq) + 2H+ + 2e− → MoO2(s) + 2H2O +0.65
O2(g) + 2H+ + 2e− → H2O2(aq) +0.70
Tl3+(aq) + 3e− → Tl(s) +0.72
H2SeO3(aq) + 4H+ + 4e− → Se(s) + 3H2O +0.74
Fe3+(aq) + e− → Fe2+(aq) +0.77
Hg22+(aq) + 2e− → 2Hg(l) +0.80
Ag+(aq) + e− → Ag(s) +0.80
NO3–(aq) + 2H+(aq) +e– → NO2(g) + H2O(l) +0.80
[AuBr4]−(aq) + 3e− → Au(s) + 4Br−(aq) +0.85
Hg2+(aq) + 2e− → Hg(l) +0.85
MnO4−(aq) + H+ + e− → HMnO4−(aq) +0.90
2Hg2+(aq) + 2e− → Hg22+(aq) +0.91
[AuCl4]−(aq) + 3e− → Au(s) + 4Cl−(aq) +0.93
MnO2(s) + 4H+ + e− → Mn3+(aq) + 2H2O +0.95
[AuBr2]−(aq) + e− → Au(s) + 2Br−(aq) +0.96
Br2(l) + 2e− → 2Br−(aq) +1.07
Br2(aq) + 2e− → 2Br−(aq) +1.09
IO3−(aq) + 5H+ + 4e− → HIO(aq) + 2H2O +1.13
[AuCl2]−(aq) + e− → Au(s) + 2Cl−(aq) +1.15
HSeO4−(aq) + 3H+ + 2e− → H2SeO3(aq) + H2O +1.15
Ag2O(s) + 2H+ + 2e− → 2Ag(s) +1.17
ClO3−(aq) + 2H+ + e− → ClO2(g) + H2O +1.18
ClO2(g) + H+ + e− → HClO2(aq) +1.19
2IO3−(aq) + 12H+ + 10e− → I2(s) + 6H2O +1.20
ClO4−(aq) + 2H+ + 2e− → ClO3−(aq) + H2O +1.20
O2(g) + 4H+ + 4e− → 2H2O +1.23
MnO2(s) + 4H+ + 2e− → Mn2+(aq) + 2H2O +1.23
Tl3+(aq) + 2e− → Tl+(s) +1.25
Cl2(g) + 2e− → 2Cl−(aq) +1.36
Cr2O72−(aq) + 14H+ + 6e− → 2Cr3+(aq) + 7H2O +1.36
CoO2(s) + 4H+ + e− → Co3+(aq) + 2H2O +1.42
2HIO(aq) + 2H+ + 2e− → I2(s) + 2H2O +1.44
BrO3−(aq) + 5H+ + 4e− → HBrO(aq) + 2H2O +1.45
2BrO3− + 12H+ + 10e− → Br2(l) + 6H2O +1.48
2ClO3− + 12H+ + 10e− → Cl2(g) + 6H2O +1.49
MnO4−(aq) + 8H+ + 5e− → Mn2+(aq) + 4H2O +1.51
HO2• + H+ + e− → H2O2(aq) +1.51
Au3+(aq) + 3e− → Au(s) +1.52
NiO2(s) + 4H+ + 2e− → Ni2+(aq) +1.59
2HClO(aq) + 2H+ + 2e− → Cl2(g) + 2H2O +1.63
Ag2O3(s) + 6H+ + 4e− → 2Ag+(aq) + 3H2O +1.67
HClO2(aq) + 2H+ + 2e− → HClO(aq) + H2O +1.67
Pb4+(aq) + 2e− → Pb2+(aq) +1.69
MnO4−(aq) + 4H+ + 3e− → MnO2(s) + 2H2O +1.70
H2O2(aq) + 2H+ + 2e− → 2H2O +1.76
AgO(s) + 2H+ + e− → Ag+(aq) + H2O +1.77
Au+(aq) + e− → Au(s) +1.83
BrO4−(aq) + 2H+ + 2e− → BrO3−(aq) + H2O +1.85
Co3+(aq) + e− → Co2+(aq) +1.92
Ag2+(aq) + e− → Ag+(aq) +1.98
S2O82- + 2e– → 2SO42- +2.07
HMnO4−(aq) + 3H+ + 2e− → MnO2(s) + 2H2O +2.09
F2(g) + 2e− → 2F−(aq) +2.87
F2(g) + 2H+ + 2e− → 2HF(aq) +3.05

Referències

  1. ↑ Milazzo, G., Caroli, S., and Sharma, V. K. (1978). Tables of Standard Electrode Potentials (Wiley, Chichester).
  2. ↑ Bard, A. J., Parsons, R., and Jordan, J. (1985). Standard Potentials in Aqueous Solutions (Marcel Dekker, New York).
  3. ↑ Bratsch, S. G. (1989). Journal of Physical Chemistry Reference Data Vol. 18, p. 1–21.
  4. ↑ Vanysek, Petr (2006). "Electrochemical Series," in Handbook of Chemistry and Physics: 87th Edition (Chemical Rubber Company).

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